第 1 季 共 13 集
播出时间：2013年4月5日
第 1 集 The Devil Arrives in Sasazuka
播出时间：2013年4月5日
When the lord of demons and his horde waged war against the humans in their realm, a hero vanquished their army. Cornered, the Devil fled through an interdimensional portal to Earth. He vows to one day reign again, but until then... he needs a job!
第 2 集 The Hero Stays at the Devil's Castle for Work Reasons
播出时间：2013年4月12日
Emilia the hero finally tracks down the ruler of demons on Earth. Meanwhile, Sadao receives a mysterious text from Chiho warning that more earthquakes are on the way.
第 3 集 The Devil Goes on a Date with His Junior in Shinjuku
播出时间：2013年4月19日
Something supernatural seems to be going on with Chiho. Meanwhile, it's possible Maou seems to have a difficult time understanding certain concepts.
第 4 集 The Hero Experiences Human Warmth
播出时间：2013年4月26日
In the aftermath of the cave-in, Emi sees a side of Maou that doesn't jive with the demonic king. Meanwhile, everyone sees a side of the landlady that nobody could have expected.
第 5 集 The Devil and the Hero Save Sasazuka
播出时间：2013年5月3日
Lucifer is wrecking the neighborhood in a big way and he's brought along some unexpected friends! Meanwhile, Emi, Maou, and Ashiya do the impossible and try to work together!
第 6 集 The Devil Climbs the Stairway to School
播出时间：2013年5月10日
Back on Ente Isla, the other high priests find out about Olba's betrayal. Meanwhile, Lucifer's moved into the Devil's Castle.
第 7 集 The Devil's Budget Is Saved by Neighborliness
播出时间：2013年5月17日
Maou and company find that a young lady named Suzuno has moved in next door. She is quick to make friends but Emi wonders what her motives are.
第 8 集 The Hero Enters the Fray
播出时间：2013年5月24日
Big problems arise when when a new fast-food restaurant opens up. Meanwhile Emi and Suzuno have many miscommunication problems.
第 9 集 The Hero Experiences a Fray
播出时间：2013年5月31日
Maou tries to handle the loss of business caused by the opening of a new restaurant. Meanwhile Emi and Suzuno need an impartial third party to resolve their dispute.
第 10 集 The Devil and the Hero Take a Break from the Daily Routine
播出时间：2013年6月7日
It's a busy day at the local amusement park, with crowded restaurants, animals on the loose, scary ghosts, and a much-needed swimwear intervention. Meanwhile, Suzuno feels the presence of a white-winged being watching her.
第 11 集 The Hero Stays True to Her Convictions
播出时间：2013年6月14日
An encounter with a stranger has Suzuno reconsidering her position on the Devil. Meanwhile, Yusa begins stalking Sadao and Shiro around town and learns that they are living good, humble lives.
第 12 集 The Devil Carries Out His Duties
播出时间：2013年6月21日
The archangel Sariel is willing to torture people to get what he wants. Soon, Satan and Sariel engage in an aerial battle that destroys half of the city.
第 13 集 The Devil and the Hero Do Some Honest Hard Work
播出时间：2013年6月28日
Ashiya has something he needs to talk to his master about in private. Meanwhile, Emi also has a strange dream where Satan conquers Sasakuza.
