第 1 季 共 24 集
播出时间：2013年4月13日
第 1 集 Revolutionary Transfer Student
播出时间：2013年4月13日
True Calendar (T.C.) 71 - A new age where 70% of the human population lives in space.
第 2 集 Beyond 666
播出时间：2013年4月20日
Enraged by his loss, Haruto uses the Valvrave to seek vengeance against the Dorssian Military. But an equally furious A-drie stands up against the attack and quickly overwhelms the inexperienced fighter.
第 3 集 L-Elf's Prophecy
播出时间：2013年4月27日
L-elf is held in interrogation but he manages to escape. Haruto makes a triumphant return and is considered a hero by the masses for taking on the Dorssian military. Haruto has a meeting with Senator Figaro.
第 4 集 The Valvrave is the Hostage
播出时间：2013年5月4日
L-elf tells Haruto to make a pact with him. ARUS kidnap Haruto and attempt to escape without saving the students of Sakimori. Shoko imparts the plans of ARUS to the student council. Not willing to depend on others, Sakimori students declare independence.
第 5 集 The Sakimori Academy Sings
播出时间：2013年5月11日
Since Shoko declared independence, the students of Sakimori have been leading a carefree lifestyle. All of a sudden, the power goes out. Finally, the students manage to turn the power back on, and they broadcast a video of themselves singing a song.
第 6 集 Saki's Comeback
播出时间：2013年5月18日
Saki goes inside the Valvrave in hopes of becoming a famous singer. She bites Haruto on the neck and then pretends to be his little sister. Dorssia forces start an attack despite Shoko's threat, while Saki pilots a female robot, which she named Carmilla.
第 7 集 Haruto Under the Ruins
播出时间：2013年5月25日
L'elf hands Shoko papers which include a plan for the military development and territorial expansion of JIOR. A-drei, Q-vier and H-neun interfere and Rukino tries to stop them. Haruto possesses L'elf to use his Valvrave.
第 8 集 Princess of Light
播出时间：2013年6月1日
Students of Sakimori are mourning for Aina. L-elf is held prisoner by the students, and he recalls the time he first met Lieselotte. Sakimori is attacked by the Dorssians. Haruto and Saki go out to battle against them, trusting L-elf's tactical advices.
第 9 集 Dog and Thunder
播出时间：2013年6月8日
L-elf has the students perform military training and establish plans to increase the defenses of Module 77. Meanwhile, Raizo is caught once again trying to hijack one of the Valvraves and is put into prison, while Kyuma dedicates himself to training in order to avenge Aina's death. Soon after, Module 77 is once again under Dorssian attack. Haruto and Saki engage the enemies unaware that they are being drawn away from the base and giving an opening for a second invading force. With Haruto and Saki occupied fighting A-Drei's party, a shortage of power renders the module defenseless until Kyuma takes control of the blue Valvrave and starts a counterattack. However, Kyuma finds himself in a disadvantage until the yellow Valvrave, piloted by Raizo, appears to assist him and they manage to drive away the enemies.
第 10 集 Campaign Promise of Love
播出时间：2013年6月15日
While in the holding bay, Takumi explains to L-elf the circumstances under which Sakimori High School was created, for Project VVV which is virtually a JIOR military initiative. As Module 77 continues to progress towards the moon, Haruto and co. discuss the terms of keeping their possession ability a secret while Shoko continues improving her relationships with their fellow schoolmates. At the same time, Rion announces that Module 77 will hold elections for a new Prime Minister that will handle their public affairs once they get to the moon, with herself along with Raizo and Satomi running as well. L-elf surprises Haruto by volunteering to take care of the election affairs since having an appointed leader would help meet his goals. Later on, the frequency at which the foreign gene within Haruto's system tries to take over increases, as noticed by Saki, and she opts to kill him should he resort to physically harming their fellow students.
第 11 集 Military Tribunal #54
播出时间：2013年6月22日
Module 77 is headed to the Moon while the students are appointed as cabinet ministers. Akira finally speaks to Shoko and it is revealed that she is Satomi's sister. Module 77 is attacked by the Dorssians and Shoko's father is held hostage by Wartenberg.
第 12 集 The Heretic Activates
播出时间：2013年6月29日
In the year 211, Saki is telling the story of the Magius to a boy who looks like L-Elf. Back to the present, Saki calmly rejects Haruto's marriage proposal and proceeds to help the other 2 Valvraves hold off the Dorssian forces. Meanwhile, the drill that was sent into the Module is moving up through the space with the intention of releasing poison gas into the atmosphere of the Module. L-Elf receives a call from Haruto and meets up with him to try to defeat the Dorssians. Satomi calls Shoko and asks her to save his sister, Akira, who is trapped in the school. Akira, who overhears this conversation, tries to stop Shoko but to no avail. Shoko was knocked unconscious by the drill while trying to get to Akira, and this prompted Akira to face her hears of being bullied and come out into the open to save Shoko. Facing a dead end due to the damage by the drill, she almost gave up until a crack in the debris reveals Valvrave unit 6.
第 13 集 A Cursed Bond
播出时间：2013年10月12日
The Chancellor of Dorssia is summoned for an audience with the Magius, where he receives unwelcome news. Meanwhile Captain Cain learns more about the Valvraves as he pilots what L-elf though was a broken unit, and Shoko faces new diplomatic challenges...
第 14 集 Siblings of the Atmosphere
播出时间：2013年10月19日
After breaking through Dorssian forces, the students of New JIOR have made it far enough to begin their decent onto Earth. However an untimely mistake throws the mission into peril, and siblings Akira and Satomi Renbokoji must face their dark past.
第 15 集 Return to Karlstein
播出时间：2013年10月26日
After crashing down to Earth, the students find themselves stranded in Dorssian territory, far from their targeted landing in JIOR. In order to infiltrate the enemy forces, L-elf uses his familiarity with his surroundings to devise a plan, however...
第 16 集 Marie Set Free
播出时间：2013年11月2日
As Marie heals from L-elf\u2019s gunshot, it becomes quickly apparent that she has a mysterious history with Valvrave Unit 01. With A-drei leading the Dorssian troops, L-elf finds his plan compromised, and Marie wrestles with losing precious memories.
第 17 集 The Rune Abyss
播出时间：2013年11月9日
After Marie pilots Unit 01, the sacrifices and consequences that come with piloting the powerful Valvrave become clear. H-neun begins to act on his suspicions of Captain Cain to protect X-eins, and Haruto must face his nightmares or give up piloting.
第 18 集 A Father's Wish
播出时间：2013年11月16日
The students devise a plan to rescue the JIORans held captive in Dorssiana, and Haruto finds that he will reunite with his somewhat estranged father. As the fateful meeting draws nearer, L-elf receives intel that prompts him to stage a reunion of his own.
第 19 集 Sadness is Like the Falling Snow
播出时间：2013年11月23日
L-elf is finally reunited with Lieselotte, however the students find themselves surrounded with Captain Cain having predicted their every move. Saki Rukino also finds herself cornered, and Haruto learns the surprising truth about the Magiuses.
第 20 集 The Kamitsuki Exposed
播出时间：2013年11月30日
The students arrive at Module 77 to a hero's welcome, complete with in-depth press coverage! Haruto and L-elf each struggle in their own way to come to terms with recent events. Meanwhile, Shoko has been fighting as well on JIOR's political battlefield.
第 21 集 The Cost of Lies
播出时间：2013年12月7日
ARUS Golden News is broadcasting the shocking events in Module 77's hangar. Dorssian chancellor declares that the residents of Module 77 are actually monsters that drain human lives. Shoko is devastated to find out that Haruto has been lying to her.
第 22 集 Fist of the Moon
播出时间：2013年12月14日
Captain Cain is tasked with the extermination of the Class 7 Special Hazard Organisms. Haruto and L-elf are on a site of a gravity reactor explosion. L-elf tries to convince Haruto that he was abandoned by his friends, but they end up blaming each other.
第 23 集 The Operation to Retake Module 77
播出时间：2013年12月21日
L-elf tries to infiltrate the enemy position but is caught by A-drei. A-drei wants him to help take out Captain Cain. In the meantime, Haruto comes back, but his memories are fading away as he continues to fight in order to expose the lies of the world.
第 24 集 Revolution to the Future
播出时间：2013年12月28日
The explosive season finale of Valvrave the Liberator.
