第 5 季 共 13 集
播出时间：2012年3月26日
第 1 集 A Little Kiss (1)
播出时间：2012年3月26日
For the Draper family, life has changed. The children must adapt to a new home, a new brother, and a new stepmother. Don seems to have everything a man could want. However, Megan, still employed at the agency, has difficulty interpreting Don's expectations for a sex kitten at home and a prim and proper employee at the office.
第 2 集 A Little Kiss (2)
播出时间：2012年3月26日
Don and Megan work out some of their issues, Roger and Pete butt heads, and Joan has a run-in with a house guest.
第 3 集 Tea Leaves
播出时间：2012年4月2日
As Sterling Cooper Draper Pryce tries to build upon its current business, Peggy is given new responsibility. Don and Harry indulge a client. Betty contemplates her mortality after seeing a doctor.
第 4 集 Mystery Date
播出时间：2012年4月9日
Don has an encounter with someone from the past. Meanwhile, Roger increases Peggy's workload, and Joan comes to a momentous decision.
第 5 集 Signal 30
播出时间：2012年4月16日
Lane attempts to land an account with Jaguar Cars, leading to a altercation with Pete. Pete and Trudy host a dinner party in the suburbs.
第 6 集 Far Away Places
播出时间：2012年4月23日
Peggy has a tough time during a particularly formidable pitch. Don calls on a potential client. Roger and Jane have an experience with LSD.
第 7 集 At the Codfish Ball
播出时间：2012年4月30日
Don is honored at a banquet for the American Cancer Society, but finds his professional reputation has been damaged. Sally lends a hand to a relative. Megan's parents come to visit from Canada.
第 8 集 Lady Lazarus
播出时间：2012年5月7日
Megan has second thoughts about her future at Sterling, Cooper, Draper, Pryce. Peggy lashes out when she's inadvertently put in the uncomfortable position of having to lie. Pete's effort to protect an acquaintance doesn't turn out quite like he expected.
第 9 集 Dark Shadows
播出时间：2012年5月14日
Don attempts to regain his creative spark, but undermines a member of his staff while doing so. Roger pursues some new clients, and in the process, hurts Jane. Betty displays her pettiness when she reveals a distressing secret to Sally.
第 10 集 Christmas Waltz
播出时间：2012年5月21日
Harry finds himself in an uncomfortable position after reconnecting with Paul Kinsey who has joined the Hare Krishnas. Lane takes drastic and unethical measures to get out of financial trouble. Don spends an afternoon with Joan to get her mind off her marital problems.
第 11 集 The Other Woman
播出时间：2012年5月28日
Pete asks Joan to make a personal and moral sacrifice to ensure the company lands the Jaguar account. Don becomes furious after learning of the impact Megan's new profession will have on their life. Feeling unappreciated, Peggy attends lunch with Freddy Rumsen, who encourages her to make a move.
第 12 集 Commissions and Fees
播出时间：2012年6月4日
Lane's shameful secret comes to the surface with dire consequences. Don recaptures his hunger for success, and Sally experiences a major milestone.
第 13 集 The Phantom
播出时间：2012年6月11日
Roger seeks to expand his affair with Megan's mother. Pete has a "last" encounter with Beth with lasting repercussions. Megan struggles to find acting work and asks for Don's help getting an audition. Peggy still seeks Don's approval.
