第 2 季 共 30 集
播出时间：1966年9月18日
第 1 集 Anatomy of a Lover
播出时间：1966年9月18日
KAOS reprograms Hymie to murder the Chief. After Max foils the attempt, and unable to go through dismantling him, he hides Hymie in his apartment. Posing as Max's cousin, Hymie meets the Chief's daughter who immediately becomes smitten with the robot. KAOS again reprograms Hymie, and this time, he's out to kill Max!
第 2 集 Strike While the Agent is Hot
播出时间：1966年9月25日
An agent dies, which leaves Max in charge of the "Spy's Guild" labor negotiations.
第 3 集 A Spy for a Spy
播出时间：1966年10月2日
A series of kidnapping take place between KAOS and CONTROL, masterminded by Siegfried. So many kidnappings take place, no one is left but Siegfried and Maxwell Smart, who must negotiate the trade of captured agents.
第 4 集 The Only Way to Die
播出时间：1966年10月9日
Max is almost killed but then CONTROL pretends that he is dead so he can complete a secret mission to protect the IRS from a bomb planted by a KAOS agent known only as the Blaster.
第 5 集 Maxwell Smart, Alias Jimmy Ballantine
播出时间：1966年10月16日
Max has to impersonate a safe cracker named Jimmy Ballantine. He has his face wrapped in bandages so KAOS won't recognise him. 99 poses as a manicurist & agent 13 is in the towel steamer. Control believes the barber shop is a KAOS front. The KAOS agents want Max to open the vault of a federal reserve bank. 99 doesn't know which one,so the Chief has all the banks vaults left unlocked. Max opens the vault, KAOS guys are removing the money & plan to kill Max,when he gets the drop on them & their plan backfires. 99 & the Chief arrive & Max accidentaly locks the Chief in the vault.
第 6 集 Casablanca
播出时间：1966年10月23日
After he is ordered to go on vacation, Max pursues the Choker to Casablanca, where he unknowingly meets 99.
第 7 集 The Decoy
播出时间：1966年10月30日
CONTROL makes KAOS believe that Max is carrying a secret code.
第 8 集 Hoo Done It
播出时间：1966年11月6日
Max and Harry Hoo try to solve a murder of an agent in a tropical hotel, but their suspects keep turning into victims.
第 9 集 Rub-a-Dub-Dub . . .Three Spies in a Sub
播出时间：1966年11月13日
Max and Agent 99 are captured by a KAOS sub commanded by Siegfried.
第 10 集 The Greatest Spy on Earth
播出时间：1966年11月20日
Max and Agent 99 go undercover to a circus in order to find a KAOS smuggling ring.
第 11 集 Island of the Darned
播出时间：1966年11月27日
86 and 99 are stranded on a KAOS controlled island where they must fight for their lives.
第 12 集 Bronzefinger
播出时间：1966年12月4日
Max has to learn about art in order to try to capture an art thief.
第 13 集 Perils in a Pet Shop
播出时间：1966年12月11日
Max is following a Kaos agent who is smuggling a parrot. While questioning the parrot he is freed by his lawyer and Max and 99 trail him to a pet shop. Max learns that the pet shop is a cover for Melnick, the Smiling Killer. They learn that the parrots are being used to memorize secret information and then smuggled out of the country.
第 14 集 The Whole Tooth and . . .
播出时间：1966年12月25日
While carrying plans for a nuclear reactor, Max runs into KAOS Agents, so he must hide the plans. Max later has to pretend to be a convict and go to jail to get them back.
第 15 集 Kiss of Death
播出时间：1967年1月1日
A women pretends to be in love with Max in order to try to kill him.
第 16 集 It Takes One to Know One
播出时间：1967年1月8日
Octavia is destroying all of the number two men of CONTROL, so Hymie becomes the new number two man.
第 17 集 Someone Down Here Hates Me
播出时间：1967年1月15日
KAOS puts up a reward to kill Max an announces that their annual party will be canceled if they don't kill him, only causing more trouble for Max.
第 18 集 Cutback at CONTROL
播出时间：1967年1月22日
The Senate is close to closing down CONTROL which leads to some agents working with KAOS.
第 19 集 The Man from YENTA
播出时间：1967年1月29日
Max is assigned to protect Miss USA, but KAOS has other plans.
第 20 集 The Mummy
播出时间：1967年2月5日
KAOS is smuggling agents into the country in mummy cases.
第 21 集 The Girls from KAOS
播出时间：1967年2月12日
KAOS is smuggling agents into the country in mummy cases.
第 22 集 Smart Fit the Battle of Jericho
播出时间：1967年2月19日
When a Control agent is killed (made to look like an accident) while undercover, Max is assigned to investigate his death and to find out how a man name Frank Lloyd Joshua is causing high-rise buildings to explode.
第 23 集 Where-What-How-Who Am I?
播出时间：1967年2月26日
86 overhears a plot to kill scientists but Max suffers amnesia in a car crash. KAOS uses a creative way to protect this information.
第 24 集 The Expendable Agent
播出时间：1967年3月5日
A British scientist who came to America to reveal a new rocket fuel formula hides at Max's apartment as KAOS tries everything they can to capture him and steal the formula.
第 25 集 How to Succeed in the Spy Business Without Really Trying
播出时间：1967年3月12日
Max and 99 are saved by Siegfried, who wants to defect. The Chief doesn't trust Siegfried until he starts to sell important information about KAOS.
第 26 集 Appointment in Sahara
播出时间：1967年3月26日
Once KAOS gets a nuclear bomb, they try to blackmail the world into disarmament, but Max and 99 are sent to save the day.
第 27 集 Pussycats Galore
播出时间：1967年4月2日
After important scientists begin to go missing, Max and 99 go undercover to solve the mystery.
第 28 集 A Man Called Smart (1)
播出时间：1967年4月9日
KAOS steals a water evaporation formula (DRY-UP) and blackmails the country by threatening to dry up all its water.
第 29 集 A Man Called Smart (2)
播出时间：1967年4月16日
Admiral Hardgrade, CONTROL's first chief, is appointed by the president to take charge of CONTROL during this crisis. He sends the Chief, Max and 99 into the field to interview Bediyoskin and learn who's behind the DryUp caper.
第 30 集 A Man Called Smart (3)
播出时间：1967年4月23日
KAOS attempts to kill the Chief in his hospital room, but a sharp-eyed 99 foils the plot. Investigating a clue at Three Brothers Omniwash, Max and 99 discover TBO means T.B.Orlando, a Hollywood executive. Or does it? When Orlando turns up dead, Max and 99 must find the truth before KAOS dries up the Mississippi River.
