第 3 季 共 26 集
播出时间：1967年9月17日
第 1 集 The Spy Who Met Himself
播出时间：1967年9月17日
KAOS's League of Impersonators are serving as duplicates for CONTROL agents, trying to steal the plans for a warhead and wreak havoc at CONTROL. After the real Max kidnapped and is replaced by an impostor, he manages to escape and a committee has to determine which is the real Max!
第 2 集 Viva Smart
播出时间：1967年9月24日
Max is set to testifie against Kaos Agent Elwood Tudbury.However Kaos is determined to stop him at all cost.
第 3 集 Witness for the Persecution
播出时间：1967年10月8日
KAOS is going to stop Smart from testifying against one of their agents.
第 4 集 The Spirit is Willing
播出时间：1967年10月15日
Max's new informer promises to deliver evidence implicating the top leader of KAOS, though it turns out that the informant has long been dead. Max must hold a seance to get his evidence.
第 5 集 Maxwell Smart, Private Eye
播出时间：1967年10月22日
With a cutback at control, everyone is taking on extra jobs.
第 6 集 Supersonic Boom
播出时间：1967年10月29日
KAOS attacks the CONTROL headquarters with a sonic boom and threatens to use it on New York City.
第 7 集 One of Our Olives is Missing
播出时间：1967年11月5日
A country singer accidentally swallows a KAOS transmitter disguised as an olive. Max has to protect her from KAOS agents.
第 8 集 When Good Fellows Get Together
播出时间：1967年11月19日
KAOS designs the world's strongest robot.
第 9 集 Dr. Yes
播出时间：1967年11月26日
Max and 99 go to Lost Lake to track down the person who is sabotaging missile launches.
第 10 集 That Old Gang of Mine
播出时间：1967年12月3日
The British CONTROL needs Max to go undercover.
第 11 集 The Mild Ones
播出时间：1967年12月10日
Max & 99 have to infiltrate a motorcycle gang called the ""Purple Knights"", because Control believes they kidnapped the Prime Minister of a foreign country while Max was guarding him.
第 12 集 Classification: Dead
播出时间：1967年12月24日
Max gets poisoned by a female KAOS agent and has to search for an antidote.
第 13 集 The Mysterious Dr. T
播出时间：1967年12月31日
When a top CONTROL scientist dies, it turns out that he wasn't the real brains behind the operations.
第 14 集 The King Lives?
播出时间：1968年1月7日
Max travels to Coronia to protect the King of Coronia from the King's evil half-brother Basil
第 15 集 The Groovy Guru
播出时间：1968年1月14日
Many of the country's teenagers are dancing constantly, under the spell of the Groovy Guru, who is helping KAOS take over the country via its teenagers. The Guru plans to incite the nation's youth to riot and destroy all government institutions.
第 16 集 The Little Black Book (1)
播出时间：1968年1月28日
Max receives a visit from his Army buddy Sid Krimm.Before he arrives however,a woman defecter from Kaos shows up to give Max a little Black Book that contains the names of various Kaos Agents.
第 17 集 The Little Black Book (2)
播出时间：1968年2月4日
Having found out that Max is a Spy, Sid who unwittingly gave what he thought was an ordinary Black Book to Kaos Agents, accompanies Max on their search for the book, and the infamous Maestro, a Top Kaos Assassin.
第 18 集 Don't Look Back
播出时间：1968年2月11日
In this take-off of The Fugitive series Max is framed by Kaos. He is charged with Bank Robbery,and Murder. This comes about when a one-handed Man (in a Maxwell Smart facemask) shoots the Bank Guard, in front of witnesses who could identify him.
第 19 集 99 Loses CONTROL
播出时间：1968年2月18日
Feeling that she has no future at Control, and no future with Max, 99 decides to leave, and accept the marriage proposal with handsome, wealthy Victor Royale. Max, feeling jealous, goes to pursue 99. Having saved Royale from an assassination attempt, Royale offers Max a job as his bodyguard.
第 20 集 The Wax Max
播出时间：1968年2月25日
Max and 99 enjoy their day off at an amusement park. Little do they realize that the Amusement Park is actually a KAOS drop-off place for secret messages.
第 21 集 Run, Robot, Run
播出时间：1968年3月3日
The Chief tells Max & 99 'Weeknews' magazine is doing a story on Control. Mr Fitzmaurice wants to accompany two Control agents on a case for his story. The Chief selects Max & 99.
第 22 集 Operation Ridiculous
播出时间：1968年3月10日
Albert Pfister starts to blow up the world using his new silent explosive.
第 23 集 Spy, Spy, Birdie
播出时间：1968年3月17日
KAOS agents disrupt an international track meet by injuring the U.S. athletes.
第 24 集 The Hot Line
播出时间：1968年3月24日
The Chief is relieved of Duty as Chief,when he receives a call from what he believes is the President;(actually it is Gorshen a Kaos voice impersonator)informing the Chief as of Today Max is the New Chief.This part of Kaos's plan to infiltrate,and then destroy Control.With Max being in charge Kaos really don't need to plan.
第 25 集 Die, Spy
播出时间：1968年3月31日
The story spoofs NBC's ""I Spy"" and Robert Culp of that series appears in a cameo role.
第 26 集 The Reluctant Redhead
播出时间：1968年4月7日
CONTROL tries to get files that contain a list of KAOS informers and agents.
