第 4 季 共 24 集
播出时间：2010年9月21日
第 1 集 Chuck Versus the Anniversary
播出时间：2010年9月21日
Chuck and Morgan go on a rogue globe-spanning mission to find Chuck’s mom. Meanwhile, Sarah and Casey follow a trail to Russia as they investigate the mysterious Volkoff Industries and its operative, Marco. Back at home, Ellie delivers big news to her family.
第 2 集 Chuck Versus the Suitcase
播出时间：2010年9月28日
When Chuck go undercover in Milan, Chuck realizes the "Achilles' Heel" in their relationship, but must set personal issues aside for the mission. Meanwhile, Morgan recognizes a fatal flaw that compromises the new Buy More. Elsewhere, Casey struggles to put down roots in Burbank.
第 3 集 Chuck Versus the Cubic Z
播出时间：2010年10月5日
Chuck and Sarah's romantic mission is canceled with the arrival of Hugo Panzer and Heather Chandler. But Chuck grows more interested when the manipulative Heather claims to know a secret about his mom. Meanwhile, as Morgan prepares the Buy More for a huge video game release, he gets a surprise from Big Mike.
第 4 集 Chuck Versus the Coup d'Etat
播出时间：2010年10月12日
Chuck and Sarah try to become better communicators as they join Ellie and Awesome on a trip to Costa Gravas; a forbidden romance may put Morgan at odds with Col. John Casey.
第 5 集 Chuck Versus the Couch Lock
播出时间：2010年10月19日
When Colonel Casey's former team returns looking for him, Chuck must decide what he's willing to sacrifice in order to find his mom. Elsewhere, Morgan works up the nerve to reveal a potentially dangerous secret to Casey.
第 6 集 Chuck Versus the Aisle of Terror
播出时间：2010年10月26日
Chuck, Sarah, Casey and Morgan must stop Dr.Stanley (Robert Englund) from releasing a toxin that induces nightmares... Chuck's mother's allegiances are questioned; Lester and Jeff celebrate Halloween at the Buy More.
第 7 集 Chuck Versus the First Fight
播出时间：2010年11月2日
After their first real fight, Chuck avoids confronting Sarah by going on a rogue mission that leads him to his mom's MI-6 handler, Gregory Tuttle, and a mysterious Russian agent. Meanwhile, Ellie is on her own mission to uncover the Bartowski family's long-buried past.
第 8 集 Chuck Versus the Fear of Death
播出时间：2010年11月16日
Afraid that his latest setback is driving a wedge between him and Sarah, Chuck resolves to prove himself by going on a dangerous mission with the overeager Agent Rye. Meanwhile, Morgan and Casey scramble as the "Buy Morons" attempt to uncover the true identity of Greta.
第 9 集 Chuck Versus Phase Three
播出时间：2010年11月23日
Chuck, Sarah, Casey and Morgan venture into the jungles of Southeast Asia when The Belgian attempts to unravel the secrets of the Intersect. Meanwhile, Captain Awesome and Ellie try to decipher a secret left behind by her father.
第 10 集 Chuck Versus the Leftovers
播出时间：2010年11月30日
It's the day after Thanksgiving and Chuck faces the most awkward of family reunions when mom comes over for dinner—along with the dangerous Alexei Volkoff. Back at the Buy More, Morgan deals with the busiest shopping day of the year as Jeff and Lester hatch their latest scheme.
第 11 集 Chuck Versus the Balcony
播出时间：2011年1月18日
Chuck tries to create a romantic getaway for Sarah while tracking down a nano-chip at a French vineyard. Lester asks Big Mike for love advice.
第 12 集 Chuck Versus the Gobbler
播出时间：2011年1月25日
Sarah takes dangerous measures to help Mary Bartowski bring down Alexei Volkoff, as Chuck worries that she may be getting in too deep. Sarah, though, must enlist the help of Chuck, Morgan and Casey to complete her undercover mission. Meanwhile, Ellie and Awesome are at odds over what to name the baby.
第 13 集 Chuck Versus the Push Mix
播出时间：2011年2月1日
The mission to take down Volkoff reaches a dangerous new level, while big changes loom at home. As Sarah works to free Chuck’s mom, Chuck and Morgan embark on their own mission to take down Alexei Volkoff. Meanwhile, Casey bonds with his daughter, Alex, while Ellie tries to ease Awesome’s anxieties over fatherhood.
第 14 集 Chuck Versus the Seduction Impossible
播出时间：2011年2月8日
Casey, Chuck and Sarah are sent to Morocco to rescue Roan Montgomery. Morgan plans to meet Alex's mother and Mary spends some time with her family.
第 15 集 Chuck Versus the Cat Squad
播出时间：2011年2月15日
Chuck surprises Sarah with her old spy team, The C.A.T. Squad, leading to a mission in Rio. As The C.A.T. Squad works to settle a score with Augusto Gaez, old secrets and grudges come to light. Back at the Buy More, Morgan fends off the advances of Carina, a former flame and frisky member of The C.A.T Squad.
第 16 集 Chuck Versus the Masquerade
播出时间：2011年2月22日
Valentine's Day is interrupted when Chuck and the team are sent on a mission to England to protect a reclusive young heiress, Vivian McArthur. Meanwhile, Casey gets an offer from the mysterious Jane Bentley. Back at home, Ellie and Awesome find an unlikely solution to a parenting problem, as Morgan ponders a big move.
第 17 集 Chuck Versus The First Bank of Evil
播出时间：2011年3月1日
Chuck encourages Vivian to get in touch with her inner villain for a mission. Morgan's search for a new roommate has unexpected results.
第 18 集 Chuck Versus the A-Team
播出时间：2011年3月15日
Chuck and Sarah suspect Casey is carrying out private missions. Chuck fears the CIA's new operatives will render him obsolete. Morgan settles in with a new roommate. Awesome becomes uncomfortable with Ellie's research.
第 19 集 Chuck Versus the Muuurder
播出时间：2011年3月22日
Chuck is put in charge of a top-priority mission, but his leadership skills are pushed to the limit when there is a murder in Castle. Meanwhile, Awesome takes on a mission of his own when Ellie finds an alarming new hobby. Elsewhere, Morgan's leadership is also tested when his Buy More troops wage war against Large Mart.
第 20 集 Chuck Versus the Family Volkoff
播出时间：2011年4月12日
With the help of his old nemesis Alexei Volkoff, Chuck and the team hunt down a deadly weapon, The Norseman. In a pre-wedding surprise, Sarah springs a pre-nup on Chuck.
第 21 集 Chuck Versus the Wedding Planner
播出时间：2011年4月19日
When Chuck and Sarah get conned out of their wedding money, there is only one man they can turn to for help -- Sarah's conman father, Jack Burton. Meanwhile, Morgan pressures Casey to face Alex's mother.
第 22 集 Chuck Versus Agent X
播出时间：2011年5月3日
Chuck and Sarah put aside spy work to have a weekend of debauchery, but Awesome’s plans for Chuck’s big night don’t go quite as expected. Meanwhile, Ellie's investigation into her father's computer leads to a life-changing discovery.
第 23 集 Chuck Versus the Last Details
播出时间：2011年5月10日
Chuck and Sarah’s wedding prep includes one final detail: ensuring that the mother-of-the-groom makes it to the ceremony alive. Meanwhile, Morgan’s responsibilities as Best Man include his most dangerous mission yet, as he faces Vivian Volkoff. Elsewhere, Ellie tends to the last details of the rehearsal dinner and seeks help from an unlikely source.
第 24 集 Chuck Versus the Cliffhanger
播出时间：2011年5月17日
Before he can kiss the bride, Chuck must enlist his wedding party to take down Vivian Volkoff and stop her from destroying the big day. When he turns to Alexei Volkoff for help, the CIA sends its toughest agent, Clyde Decker, to stop them.
